Authors: Thomas A. Dunder, Ph.D. | February 5, 2021

In January 2021, the EPA issued draft method OTM-45, the first air emissions test method designed specifically for per- and polyfluoroalkyl substances (PFAS). The method provides detailed guidance to testers and laboratories to measure low concentrations of multiple PFAS compounds. Numerous stationary sources have been implicated in PFAS emissions that have resulted in deposition with subsequent water and soil contamination as well as human exposure. These facilities have included a wide range of industries, such as plants manufacturing fluorinated chemicals, manufacturers who utilize PFAS compounds in coatings and other water- and stain-resistant products, metal plating, incinerators, and hazardous waste combustors. There is a significant quantity of PFAS wastes, including millions of gallons of aqueous film forming foam (AFFF), awaiting disposal. The OTM-45 method will be used as one tool to determine if and how PFAS waste can be safely disposed of or destroyed. Other air emissions sources suspected of containing PFAS compounds can now be evaluated, allowing appropriate emissions control devices to be installed to greatly limit PFAS contamination of the atmosphere and the environment.

The method is based on a similar test method (SW846 Method 0010 for semi-volatile organic compounds) with several notable changes. In the OTM-45 method, a modified Method 5 sampling train is used to collect PFAS compounds in several fractions which are analyzed separately. This train includes two sorbent cartridges utilizing XAD-2 to capture and concentrate PFAS compounds (the second cartridge serves to assess breakthrough of any PFAS collected on the first cartridge and the impingers), a filter, probe and nozzle rinse, impingers charged with highly purified water, and one impinger with silica gel. Analysis is conducted using liquid chromatography/dual mass spectrometry (LC/MS/MS).

PFAS compounds are both ubiquitous in the environment and present in many commonly used materials in stack testing and laboratory procedures. Detailed procedures are provided to minimize sample and analytical contamination by avoiding fluorine containing materials such as Teflon and utilizing specific cleaning methodologies for glassware and other materials that may contact the samples. Extensive quality assurance procedures are included to verify absence of contamination via the analysis of blanks for air sampling media, rinse solvents, and blank trains.

Quantitative Reporting Limits (QRLs) ranging from 1.5 to 2.5 nanograms (ng) per sampling train are quoted for 26 different PFAS compounds. Significantly higher QRLs were quoted for two additional PFAS compounds. Emission rate detection limits will be determined by the combination of laboratory detection capabilities and the volume of stack gas sampled. Although QRLs are provided for only 28 PFAS compounds, the method lists 50 PFAS compounds that can be detected; currently detection is limited by the availability of quantitative laboratory standards. TRC anticipates that the list of applicable analytes will expand considerably as laboratory capabilities are further developed. EPA has acknowledged that this draft method will continue to be evaluated and will evolve as testing programs are conducted and the results evaluated. In an unusual step, EPA has requested the submission of test reports from projects utilizing the method to evaluate performance.

TRC’s Air Measurement Services testing teams are well versed in the procedures incorporated in OTM-45 and immediately ready to conduct test programs using the method.

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Per‐ and Polyfluoroalkyl Substances in Environmental Sampling Products: Fact or Fiction?

March 29, 2022

Can per‐ and polyfluoroalkyl substances (PFAS) be transferred from the common field and other commercial products during sampling?

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Insights

Evaluation of the Effects of PFAS Soil Adsorption and Transformation

March 29, 2022

A study to to evaluate the effect of divalent cations on the adsorption of per- and polyfluoroalkyl substances (PFAS) onto soil particles.

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Insights

PFAS Experts Symposium 2: An Update on Advances in Chemical Analysis of PFAS

March 23, 2022

A recap of how the analysis of per‐ and polyfluoroalkyl substances (PFAS) has evolved since the first PFAS Experts Symposium in 2019.

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Insights

PFAS Experts Symposium: Regulations and Technologies

March 23, 2022

The scientific, engineering, regulatory, and legal communities assembled for the PFAS Experts Symposium in Arlington, Virginia to discuss issues related to per‐ and polyfluoroalkyl substances (PFAS).

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Insights

Draft Environmental Protection Agency (EPA) Method 1633: A Data User’s Perspective

March 15, 2022

A review of Draft EPA Method 1633, Analysis of Per‐and Polyfluoroalkyl Substances (PFAS) in Aqueous, Solid, Biosolids, and Tissue Samples by LC‐MS/MS

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Regulatory Updates

PFOA & PFOS As CERCLA Hazardous Substances: What Does This Mean and How Can You Be Prepared?

February 17, 2022

A plan to designate two per- and polyfluoroalkyl substances (PFAS) as “hazardous substances” under CERCLA was recently submitted by the EPA.

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Regulatory Updates

New Phase I ESA Standard Will Affect Environmental Due Diligence

January 25, 2022

After years of review, revisions and discussions, the new ASTM E1527 Phase I Environmental Site Assessment (Phase I ESA) standard has been published. The new standard includes updates to definitions, clarifications on processes and requirements, and guidance for emerging contaminants.

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Regulatory Updates

Fifth Unregulated Contaminant Monitoring Rule Lists 29 PFAS

January 21, 2022

EPA published fifth Unregulated Contaminant Monitoring Rule as required every five years and 29 of the 30 contaminants listed are PFAS.

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Insights

Need help collecting PFAS samples for NJDEP deadline December 15?

October 7, 2021

NJDES Category B or L Industrial Permit holders – If you haven’t obtained your first PFAS sample yet, time is running out. All New Jersey Pollutant Discharge Elimination System (NJDES) Category B or L Industrial Permit holders are required by the New Jersey Department of Environmental Projection (NJDEP) to collect two representative effluent samples, taken 30 days apart, to be analyzed for PFAS by an approved laboratory and submitted to them by December 15, 2021.

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Regulatory Updates

Interpretation of “Waters of the United States” (WOTUS) Reverts to Pre-2015 Regulatory Definition

September 29, 2021

Environmental Protection Agency (EPA) and U.S. Army Corps of Engineers (ACOE) revert to pre-2015 regulatory program definition of “Waters of the United States.”

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Regulatory Updates

EPA Solicits Comments on PFAS Discharges in Five Point Source Categories

September 23, 2021

EPA solicits comments in five point source categories (PSCs) in the manufacture, use, treatment and discharge of PFAS.

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Regulatory Updates

PFAS Air Emissions Standards and Trends for Summer 2021

August 17, 2021

Environmental impacts of PFAS in ambient air leads to states implementing PFAS air-related thresholds.

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Insights

Cryptocurrency: The Environmental Threats and Opportunities

August 9, 2021

Cryptocurrency (also known as crypto) is taking the fintech industry by storm, despite the economic experts who still dismiss it as a viable form of currency. Although often criticized for this volatility, whistleblowers are also further shining a light on the severe toll that these digital currencies are taking on the environment.

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White Papers / Reports

TRC Colorado PFAS Regulatory Update

July 21, 2021

Update on Colorado’s recent policies and plans to regulate new and historical discharges of per- and polyfluoroalkyl substances (PFAS) into the environment.

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Regulatory Updates

2021 EPA TRI Reporting Requirements for Natural Gas Processing Facilities

July 12, 2021

Indication EPA finalizing a rule to add natural gas extraction or processing plants to EPCRA Toxics Release Inventory (TRI) reporting.

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Insights

Implementing bioremediation at environmental cleanup sites: TRC experts weigh in at leading industry conference

May 17, 2021

TRC experts make several presentations at the Battelle conference about innovative approaches they have developed for implementing and monitoring bioremediation and the use of naturally-occurring or deliberately-introduced micro-organisms to break down environmental pollutants.

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Videos

PFAS Compounds & Toxics Release Inventory

April 26, 2021

The National Defense Authorization Act of 2020 added 172 PFAS compounds to the list of chemicals that must be evaluated for reporting.

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Insights

PFAS Sampling Advisory on Aqueous Samples

April 1, 2021

Advisory on collecting aqueous samples (e.g., groundwater, wastewater, stormwater, etc.) for PFAS analysis.

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Regulatory Updates

Interim Guidance on Destruction and Disposal of PFAS & Materials Containing PFAS

February 19, 2021

Interim Guidance from EPA identifies 6 materials that use or manufacture PFAS and approaches for disposal.

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Insights

EPA Issues PFAS Air Emissions Draft Test Method OTM-45

February 5, 2021

First Air Emissions Draft Test for the Measurement of Selected Per- and Polyfluorinated Alkyl Substances from Stationary Sources

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Resources

Microplastics Fate and Transport

January 31, 2021

This presentation discusses the fate and transport of microplastics and provides case studies of microplastic sampling projects.

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Regulatory Updates

EPA continues to aggressively address PFAS wastewater with two new strategies

January 4, 2021

EPA takes steps toward PFAS wastewater and storm water permitting, and analytical methods for testing.

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Videos

PFAS at Metal-Plating Facilities: Environmental Management and Regulatory Developments

November 13, 2020

TRC is a national leader in per- and poly-fluoroalkyl substances (PFAS) characterization, research and technical consulting.

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News

TRC Companies Inc. Acquires 1Source Safety and Health

November 11, 2020

TRC Companies (“TRC”), a leading technology-driven provider of end-to-end engineering, consulting and construction management solutions, has acquired 1Source Safety and Health, a firm that provides management consulting services in areas such as indoor air quality, asbestos management, industrial hygiene and safety management systems.

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Ecological Risk of PFAS from AFFF-Impacted Sites

June 30, 2020

The facts on evaluating exposure to wildlife

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TRC’s Reporting Tool Can Help Identify New PFAS under the TRI

May 19, 2020

While utilities often work in technical silos, NERC auditors are trained to cross check compliance evidence and data between interrelated standards.

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Insights

World Health Organization Examines Danger of Microplastics in Drinking Water

November 5, 2019

There’s growing concern that microscopic plastic particles could be having a detrimental effect on drinking water quality.

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Insights

Michigan Steps Up Fight Against PFAS Contamination

May 8, 2018

Michigan is cracking down on PFAS contamination with a pair of new regulatory actions aimed at protecting the state’s water supply.

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Insights

Risk Assessments for Your Environmental Permit

February 1, 2024

Environmental risk assessments help protect facilities, workers and the environment. Learn more about the importance of environmental risk assessments today.

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Insights

Filling Vapor Intrusion Data Gaps During Property Transaction Due Diligence

October 18, 2023

Environmental due diligence for property transactions is an incredibly dynamic business process

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Insights

Environmental Site Assessments for Forest and Rural Properties

July 25, 2023

Key considerations for leveraging ASTM E2247 vs. E1527

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Insights

The Rise of Agrivoltaics

July 18, 2023

This article explores the tensions between traditional agriculture and solar development, as well as the financial benefits for farmers who lease their land for solar projects.

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Regulatory Updates

Changes to EPA’s Risk Management Program (RMP) Regulations Are Coming

April 14, 2023

Changes to the Risk Management Program (RMP) regulations were signed into a final rule on February 27, 2024, by EPA Administrator Michael S. Regan.

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Insights

Routinely Evaluating the Health & Effectiveness of Integrated Systems to Manage EHS/ESG Risks – Part 2

March 15, 2023

Systematic monitoring and continuous improvement is important to achieve an effective EHS/ESG management system within an organization.

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Regulatory Updates

Deadline Approaching for Utilities to Report SF₆ Emissions to EPA

March 8, 2023

The EPA regulates greenhouse gas (GHG) emissions under the Greenhouse Gas Reporting Program (GHGRP) and has recently decided to place renewed emphasis on sulfur hexafluoride (SF₆).

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Insights

Recognizing, Identifying, Prioritizing and Addressing EHS & ESG Risks

March 3, 2023

A clear view and understanding of the environmental, health and safety (EHS) risks created by a business is paramount to its success and longevity.

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Insights

Routinely Evaluating the Health & Effectiveness of Integrated Systems to Manage EHS/ESG Risks – Part I

March 1, 2023

Once established, an EHS/ESG management system must be routinely evaluated to ensure it remains effective to identify and control risks, as well as accommodate and adjust for changes that occur to/within the organization.

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Resources

ASTM Phase I Environmental Site Assessment Updates

February 1, 2023

Environmental due diligence is the first step in identifying potential environmental liabilities prior to the acquisition of real estate or business transfers.

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Regulatory Updates

Phase I ESA ASTM Standard Update: The Wait is Over

December 21, 2022

The USEPA published a Final Rule making the ASTM E1527-21 Phase I ESA standard AAI compliant.

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Insights

Optimizing EHS/ESG Information Management and Reporting Systems by Leveraging Innovative Digital Technology Solutions

August 10, 2022

A single, integrated enterprise wide EHS/ESG IMS can significantly improve performance and communicate progress towards organizational requirements and goals.

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Insights

Regulatory Compliance Items to Consider as Part of Transactional Due Diligence

July 19, 2022

Performing a limited environmental regulatory review can identify potential deficiencies with the environmental management of an acquisition.

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Insights

Support an Integrated EHS/ESG Management System

June 10, 2022

While a Phase I Environmental Site Assessment (ESA) is a common method for identifying environmental liabilities during transactional due diligence, the ASTM International standard for Phase I ESAs (E1527-13, with proposed E1527-21 awaiting adoption) omits regulatory compliance from its scope. For properties containing operations that may be applicable to environmental compliance regulations, performing a limited environmental regulatory review can identify potential deficiencies with the environmental management of the facility. A limited environmental compliance review typically evaluates the presence of material findings that may exist in a facility’s management of its environmental compliance requirements. Material findings are defined as a condition of non-compliance that could necessitate expenditures, not including attorney fees or regulatory agency penalties, in excess of a specified dollar amount or materiality threshold. The materiality threshold is based on the client’s risk tolerance and is often in the range of $50,000. However, this amount is arbitrary and can be revised as appropriate. Non-material deficiencies, those identified below the materiality threshold, would still require action but are within the client’s risk tolerance.

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Insights

How to Use an Integrated Approach To Manage EHS and ESG Risks

April 20, 2022

While a Phase I Environmental Site Assessment (ESA) is a common method for identifying environmental liabilities during transactional due diligence, the ASTM International standard for Phase I ESAs (E1527-13, with proposed E1527-21 awaiting adoption) omits regulatory compliance from its scope. For properties containing operations that may be applicable to environmental compliance regulations, performing a limited environmental regulatory review can identify potential deficiencies with the environmental management of the facility. A limited environmental compliance review typically evaluates the presence of material findings that may exist in a facility’s management of its environmental compliance requirements. Material findings are defined as a condition of non-compliance that could necessitate expenditures, not including attorney fees or regulatory agency penalties, in excess of a specified dollar amount or materiality threshold. The materiality threshold is based on the client’s risk tolerance and is often in the range of $50,000. However, this amount is arbitrary and can be revised as appropriate. Non-material deficiencies, those identified below the materiality threshold, would still require action but are within the client’s risk tolerance.

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Regulatory Updates

New Phase I ESA Standard Will Affect Environmental Due Diligence

January 25, 2022

After years of review, revisions and discussions, the new ASTM E1527 Phase I Environmental Site Assessment (Phase I ESA) standard has been published. The new standard includes updates to definitions, clarifications on processes and requirements, and guidance for emerging contaminants.

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White Papers / Reports

Managing EHS & ESG Risks Through Integrated Systems Today and Beyond

July 22, 2021

It has been more than 50 years since the development and establishment of the federal Environmental Protection Agency (EPA) and the federal Occupational Safety & Health Administration (OSHA) which were formed to protect our environment and workplaces across the United States. Significant laws, policies and regulations followed to establish the “regulatory programs” that all applicable businesses and entities must address and meet to ensure these compliance-driven legislative programs would create a foundation to protect our society.

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Insights

Environmental Impacts of Transitioning to Renewables

May 15, 2021

The transition to renewable energy sources will have notable environmental impacts as well as economic impacts. To understand the possible implications, you’ll need some background knowledge of the ways fossil fuels affect the environment.

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Insights

Controlling volatile organic emissions from RCRA hazardous waste activities

May 14, 2021

EPA identifies National Compliance Initiative FY2020-2023 for reducing hazardous air emissions from hazardous waste facilities.

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Insights

PFAS Sampling Advisory on Aqueous Samples

April 1, 2021

Advisory on collecting aqueous samples (e.g., groundwater, wastewater, stormwater, etc.) for PFAS analysis.

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Regulatory Updates

Interim Guidance on Destruction and Disposal of PFAS & Materials Containing PFAS

February 19, 2021

Interim Guidance from EPA identifies 6 materials that use or manufacture PFAS and approaches for disposal.

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Insights

EPA Issues PFAS Air Emissions Draft Test Method OTM-45

February 5, 2021

First Air Emissions Draft Test for the Measurement of Selected Per- and Polyfluorinated Alkyl Substances from Stationary Sources

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News

TRC Companies Inc. Expands Environmental and Renewable Energy Capabilities with the Acquisition of Shoener Environmental

December 2, 2020

Today TRC Companies, announces the expansion of its environmental and renewable energy capabilities with the acquisition of Shoener Environmental.

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Videos

TRC Talks – Renewable Energy

November 24, 2020

Our experts discuss TRC’s integrated approach to renewable energy development.

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News

TRC Companies Inc. Acquires 1Source Safety and Health

November 11, 2020

TRC Companies (“TRC”), a leading technology-driven provider of end-to-end engineering, consulting and construction management solutions, has acquired 1Source Safety and Health, a firm that provides management consulting services in areas such as indoor air quality, asbestos management, industrial hygiene and safety management systems.

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Tom Dunder

Tom Dunder is Technical Director in the Air Management Services Division at TRC Companies in Raleigh, North Carolina where he performs and manages air pollutant testing programs. He has degrees in Chemistry from Columbia (A.B.), Rutgers (M.S.) and the University of North Carolina (Ph.D.). Tom has 29 years of experience in gaseous pollutant emissions measurements at a wide variety of industries (refineries, chemical plants, power plants, paper mills, etc.) with recent work in biomass/biogas processes and emerging pollutants like PFAS. Contact Tom at tdunder@trcsolutions.com.